{"id":589251,"date":"2022-04-11T08:03:31","date_gmt":"2022-04-11T08:03:31","guid":{"rendered":"https:\/\/www.indcareer.com\/schools\/?p=589251"},"modified":"2022-04-11T08:03:33","modified_gmt":"2022-04-11T08:03:33","slug":"s-block-elements-sodium-carbonate-washing-soda-na2co3","status":"publish","type":"post","link":"https:\/\/www.indcareer.com\/schools\/s-block-elements-sodium-carbonate-washing-soda-na2co3\/","title":{"rendered":"s-Block Elements: Sodium Carbonate (Washing soda) (Na2CO3):"},"content":{"rendered":"\n<h2 class=\"wp-block-heading\" id=\"h-a-preparation\">a) Preparation:<\/h2>\n\n\n\n<p><strong>Solvay process:<\/strong><\/p>\n\n\n\n<p>Carbon dioxide gas is bubbled through a brine solution saturated with ammonia and itresults in the formation of sodium hydrogen carbonate.<\/p>\n\n\n\n<p>NH3 + H2O + CO2 \u2192 NH4HCO3<\/p>\n\n\n\n<p>NaCI + NH4HCO3 \u2192 NaHCO3 + NH4CI<\/p>\n\n\n\n<p>Sodium hydrogen carbonate so formed precipitates out because of the common ion effect caused due to the presence of excess of NaCl. The precipitated NaHCO3 is filtered off and then ignited to get Na2CO3.<br>2NaHCO3 \u2192 Na2CO3 + CO2 + H2O<\/p>\n\n\n\n<h2 class=\"wp-block-heading\">b) Properties<\/h2>\n\n\n\n<ol class=\"wp-block-list\"><li>The aqueous solution absorbs CO2 yielding sparingly soluble sodium bicarbonate. Na2CO3 + H2O + CO2 \u2192 2NaHCO\u00ad3<\/li><li>dissolves in acids with an effervescence of carbondioxide and is causticised by lime to give caustic soda.<\/li><\/ol>\n\n\n\n<p>Na2CO3 + 2HCl \u21922NaCl + H2O + CO2<\/p>\n\n\n\n<p>Na2CO3 + Ca(OH)2 \u2192 2NaOH + CaCO3<\/p>\n\n\n\n<ol class=\"wp-block-list\" start=\"3\"><li>Fusion with silica, sodium carbonate yields sodium silicate.<\/li><\/ol>\n\n\n\n<p>Na2CO3 + SiO2 \u2192 Na2SiO3 + CO\u00ad2<\/p>\n\n\n\n<ol class=\"wp-block-list\" start=\"4\"><li><strong>Hydrolysis<\/strong> \u2013 being a salt of a strong base (NaOH) and weak acid (H2CO3), when dissolved in water sodium carbonate. Undergoes hydrolysis to form an alkaline solution<\/li><\/ol>\n\n\n\n<p>Na2CO3 + 2H2O\u2192 H2CO3 + 2NaOH<br>c) Uses<\/p>\n\n\n\n<p>It is used for softening hard water.<\/p>\n\n\n\n<p>A mixture of sodium carbonate &amp; potassium carbonate is used as fusion mixture.<\/p>\n\n\n\n<p>As an important laboratory reagent both in qualitative and quantitative analysis.<\/p>\n\n\n\n<p>It is used in paper, paints and textile industries.<\/p>\n\n\n\n<p>It is used for washing purposes in laundry.<\/p>\n\n\n\n<p>It is used in the manufacture of glass, borax, soap and caustic soda.<\/p>\n\n\n\n<p>Alkali Earth Metals (Group II elements of modern periodic table):<br>Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba) and Radium (Ra).<\/p>\n\n\n\n<h2 class=\"wp-block-heading\">Physical Properties of Alkali Earth Metals:<\/h2>\n\n\n\n<ol class=\"wp-block-list\"><li><strong>Alkali earth metals are almost similar in properties to the corresponding alkali metals.<\/strong><\/li><\/ol>\n\n\n\n<p>Higher melting points than alkali metals<\/p>\n\n\n\n<p>Higher boiling points alkali metals<\/p>\n\n\n\n<p>Higher densities alkali metals<\/p>\n\n\n\n<p>Harder than the corresponding alkali metals<\/p>\n\n\n\n<ol class=\"wp-block-list\" start=\"2\"><li><strong>Atomic and ionic radii<\/strong><\/li><\/ol>\n\n\n\n<p>The atomic radii as well as ionic radii of the members of the family are smaller than the corresponding members of alkali metals.<\/p>\n\n\n\n<ol class=\"wp-block-list\" start=\"3\"><li><strong>Ionization energy:<\/strong> The alkaline earth metals owing to their large size of atoms have fairly low values of ionization energies as compared to the p \u2013 block elements. However with in the group, the ionization energy decreases as the atomic number increases. It is because of increase in atomic size due to addition of new shells and increase in the magnitude of screening effect of the electrons in inner shells. Because their (IE)1 is larger than that of their alkali metal neighbours, the group IIA metals trend to the some what less reactive than alkali metals. The general reactivity trend is Ba > Sr > Ca > Mg > Be.<\/li><li><strong>Oxidation state: <\/strong>The alkaline earth metal have two electrons in their valence shell and by losing these electrons, these atoms acquire the stable noble gas configuration. Thus, unlike alkali metals, the alkaline earth metals exhibit +2 oxidation state in their compounds.<\/li><\/ol>\n","protected":false},"excerpt":{"rendered":"<p>a) Preparation: Solvay process: Carbon dioxide gas is bubbled through a brine solution saturated with ammonia and itresults in the formation of sodium hydrogen carbonate. NH3 + H2O + CO2 \u2192 NH4HCO3 NaCI + NH4HCO3 \u2192 NaHCO3 + NH4CI Sodium hydrogen carbonate so formed precipitates out because of the common ion effect caused due to [&hellip;]<\/p>\n","protected":false},"author":304,"featured_media":589272,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"newspack_featured_image_position":"","newspack_post_subtitle":"","newspack_article_summary_title":"Overview:","newspack_article_summary":"","newspack_hide_updated_date":false,"newspack_show_updated_date":false,"footnotes":""},"categories":[2203],"tags":[],"boards":[],"class_list":["post-589251","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-study","entry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v27.0 (Yoast SEO v27.1.1) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>s-Block Elements: Sodium Carbonate (Washing soda) (Na2CO3): - 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